Inorganic Chemistry
Inorganic Chemistry
5 years ago

Iron(III) Ejection from a “Beheaded” TAML Activator: Catalytically Relevant Mechanistic Insight into the Deceleration of Electrophilic Processes by Electron Donors

Iron(III) Ejection from a “Beheaded” TAML Activator: Catalytically Relevant Mechanistic Insight into the Deceleration of Electrophilic Processes by Electron Donors
Alexander D. Ryabov, Terrence J. Collins, David Z. Zhang, Longzhu Q. Shen, Matthew R. Mills
Replacement of the aromatic moiety of TAML catalysts with an aliphatic unit makes the HOMO of the “beheaded” TAML evenly distributed via in-plane nitrogens, changes the transition state for proton delivery from late to early, and increases 1 × 104-fold its resistance to the acid-induced demetalation.

Publisher URL: http://dx.doi.org/10.1021/acs.inorgchem.7b00921

DOI: 10.1021/acs.inorgchem.7b00921

You might also like
Discover & Discuss Important Research

Keeping up-to-date with research can feel impossible, with papers being published faster than you'll ever be able to read them. That's where Researcher comes in: we're simplifying discovery and making important discussions happen. With over 19,000 sources, including peer-reviewed journals, preprints, blogs, universities, podcasts and Live events across 10 research areas, you'll never miss what's important to you. It's like social media, but better. Oh, and we should mention - it's free.

  • Download from Google Play
  • Download from App Store
  • Download from AppInChina

Researcher displays publicly available abstracts and doesn’t host any full article content. If the content is open access, we will direct clicks from the abstracts to the publisher website and display the PDF copy on our platform. Clicks to view the full text will be directed to the publisher website, where only users with subscriptions or access through their institution are able to view the full article.