3 years ago

Iron(III) Ejection from a “Beheaded” TAML Activator: Catalytically Relevant Mechanistic Insight into the Deceleration of Electrophilic Processes by Electron Donors

Iron(III) Ejection from a “Beheaded” TAML Activator: Catalytically Relevant Mechanistic Insight into the Deceleration of Electrophilic Processes by Electron Donors
Alexander D. Ryabov, Terrence J. Collins, David Z. Zhang, Longzhu Q. Shen, Matthew R. Mills
Replacement of the aromatic moiety of TAML catalysts with an aliphatic unit makes the HOMO of the “beheaded” TAML evenly distributed via in-plane nitrogens, changes the transition state for proton delivery from late to early, and increases 1 × 104-fold its resistance to the acid-induced demetalation.

Publisher URL: http://dx.doi.org/10.1021/acs.inorgchem.7b00921

DOI: 10.1021/acs.inorgchem.7b00921

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