Axially Assembled Photosynthetic Antenna-Reaction Center Mimics Composed of Boron Dipyrromethenes, Aluminum Porphyrin, and Fullerene Derivatives

5 years ago

Axially Assembled Photosynthetic Antenna-Reaction Center Mimics Composed of Boron Dipyrromethenes, Aluminum Porphyrin, and Fullerene Derivatives

Georgios Charalambidis, Vasilis Nikolaou, Habtom B. Gobeze, Francis D’Souza, Nikos Tagmatarchis, Athanassios G. Coutsolelos, Christina Stangel, Anastasios Stergiou, Anthi Bagaki, Asterios Charisiadis

Sequential photoinduced energy transfer followed by electron transfer leading to the formation of charge separated states in a newly assembled series of supramolecular triads comprised of boron dipyrromethenes (BODIPY or BDP), aluminum porphyrin (AlTPP), and C₆₀ is demonstrated.

Publisher URL: http://dx.doi.org/10.1021/acs.inorgchem.7b01050

DOI: 10.1021/acs.inorgchem.7b01050

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