3 years ago

S,O-Ligand-Promoted Palladium-Catalyzed C–H Functionalization Reactions of Nondirected Arenes

S,O-Ligand-Promoted Palladium-Catalyzed C–H Functionalization Reactions of Nondirected Arenes
Carolina Valderas, Kananat Naksomboon, M. Ángeles Fernández-Ibáñez, Melania Gómez-Martínez, Yolanda Álvarez-Casao
Pd(II)-catalyzed C–H functionalization of nondirected arenes has been realized using an inexpensive and easily accessible type of bidentate S,O-ligand. The catalytic system shows high efficiency in the C–H olefination reaction of electron-rich and electron-poor arenes. This methodology is operationally simple, scalable, and can be used in late-stage functionalization of complex molecules. The broad applicability of this catalyst has been showcased in other transformations such as Pd(II)-catalyzed C–H acetoxylation and allylation reactions.

Publisher URL: http://dx.doi.org/10.1021/acscatal.7b02356

DOI: 10.1021/acscatal.7b02356

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