3 years ago

Diastereo- and enantioselective additions of [small alpha]-nitro esters to imines for anti-[small alpha],[small beta]-diamino acid synthesis with [small alpha]-alkyl-substitution

Diastereo- and enantioselective additions of [small alpha]-nitro esters to imines for anti-[small alpha],[small beta]-diamino acid synthesis with [small alpha]-alkyl-substitution
Anand Singh, Jeffrey N. Johnston, Daniel J. Sprague
The discovery that a C2-symmetric bis(AMidine) [BAM] catalyst promotes an anti-selective addition of [small alpha]-substituted [small alpha]-nitro esters to imines is described, providing [small alpha]-substituted [small alpha],[small beta]-diamino ester products with high diastereo- and enantioselectivity.

Publisher URL: http://feeds.rsc.org/~r/rss/SC/~3/M4nR_CVZEUc/C7SC05176J

DOI: 2018/SC/C7SC05176J

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