3 years ago

pH-Dependent Modulation of Reactivity in Ruthenium(II) Organometallics

pH-Dependent Modulation of Reactivity in Ruthenium(II)
Timothy J. Prior, Benjamin S. Murray, Ross W. Boyle, Huguette Savoie
The pH-dependent intramolecular chelation of a tethered sulfonamide ligand in ruthenium(II) arene complexes is demonstrated, a process shown to modulate metal-centered reactivity toward the model ligand guanosine 5′-monophosphate within the physiologically relevant pH region.

Publisher URL: http://dx.doi.org/10.1021/acs.organomet.7b00868

DOI: 10.1021/acs.organomet.7b00868

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