5 years ago

Phosphinoyl Radical-Initiated α,β-Aminophosphinoylation of Alkenes

Phosphinoyl Radical-Initiated α,β-Aminophosphinoylation of Alkenes
Jian-Ping Zou, Jian-An Li, Wei Zhang, Kui Liu, Pei-Zhi Zhang, Adedamola Shoberu
A new double functionalization reaction of alkenes through AgNO3-mediated phosphinoyl radical addition followed by Cu(II)-catalyzed amination is introduced. This one-pot, three-component reaction is performed under mild conditions to afford α,β-aminophosphinoylation products.

Publisher URL: http://dx.doi.org/10.1021/acs.orglett.7b02183

DOI: 10.1021/acs.orglett.7b02183

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