Inorganic Chemistry
Inorganic Chemistry
5 years ago

Design of a Binuclear Ni(II) Complex with Large Ising-type Anisotropy and Weak Anti-Ferromagnetic Coupling

Design of a Binuclear Ni(II) Complex with Large Ising-type Anisotropy and Weak Anti-Ferromagnetic Coupling
Fatima El-Khatib, Hala Hafez, Maurici López-Jordà, Benjamin Cahier, Nathalie Guihéry, Jean-Jacques Girerd, Eric Rivière, Zeinab Saad, Régis Guillot, Talal Mallah
The cryptand ligand bearing two tetradentate coordination sites together with the imidazolate bridge allow designing a binuclear Ni(II) complex with large Ising-type anisotropy, nearly collinear local easy magnetization axes, and weak anti-ferromagnetic coupling.

Publisher URL: http://dx.doi.org/10.1021/acs.inorgchem.7b01609

DOI: 10.1021/acs.inorgchem.7b01609

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