Tetrahedron
Tetrahedron
5 years ago

Stereoselective synthesis of the right-hand cores of 16-methylated oxazolomycins

Stereoselective synthesis of the right-hand cores of 16-methylated oxazolomycins
The right-hand heterocyclic cores of oxazolomycins having either 16R or 16S-methyl group configurations on the β-lactones were stereoselectively synthesized from the common intermediate utilized for our previous syntheses of neooxazolomycin and oxazolomycin A. In addition, the right-hand segment required for the synthesis of KSM-2690 and lajollamycin members was also synthesized in a stereoselective manner.

Publisher URL: www.sciencedirect.com/science

DOI: S0040402017313042

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