Journal of Organometallic Chemistry
Journal of Organometallic Chemistry
5 years ago

First molecular conductors of BPDT-TTF with metallacarborane anions: (BPDT-TTF)[3,3′-Сr(1,2-C2B9H11)2] and (BPDT-TTF)[3,3′-Сo(1,2-C2B9H11)2] – Synthesis, structure, properties

First molecular conductors of BPDT-TTF with metallacarborane anions: (BPDT-TTF)[3,3′-Сr(1,2-C2B9H11)2] and (BPDT-TTF)[3,3′-Сo(1,2-C2B9H11)2] – Synthesis, structure, properties
The first molecular conductors based on bis(1,3-propylenedithio)tetrathiafulvalene and transition metal bis(dicarbollides) (BPDT-TTF)[3,3′-Сr (1,2-C2B9H11)2] (1) and (BPDT-TTF)[3,3′-Сo (1,2-C2B9H11)2] (2) were synthesized and their crystal structures were determined by X-ray analysis. The electric conductivity measurements revealed that these compounds are semiconductors at room temperature.

Publisher URL: www.sciencedirect.com/science

DOI: S0022328X18300688

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