Angewandte Chemie - International Edition
Angewandte Chemie - International Edition
5 years ago

An Expanded Porphycene with High NIR Absorptivity That Stabilizes Two Different Kinds of Metal Complexes

An Expanded Porphycene with High NIR Absorptivity That Stabilizes Two Different Kinds of Metal Complexes
Vincent D. Lynch, Jonathan L. Sessler, Gonzalo Anguera, Dongho Kim, Matthew D. Moore, Michael Y. Zhao, Won-Young Cha, James T. Brewster
Porphycene, first reported by Emanuel Vogel, was the first fully characterized porphyrin isomer. In contrast to what has proved true for porphyrins, efforts to expand the porphycene core have proved limited. In their Communication (DOI: 10.1002/anie.201711197), J. L. Sessler, D. Kim, and co-workers describe a new approach to extending the porphycene core. As with the accordion on which the illustration is based, the result is beautiful music in terms of new metal coordination chemistry.

Publisher URL: http://onlinelibrary.wiley.com/resolve/doi

DOI: 10.1002/anie.201800781

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