A Rare Heterobimetallic Ca–Ag Coordination Polymer as Sensitive Luminescence Sensor for TNP
Abstract
The present work reports the synthesis, characterization, and crystal structure of a rare 2-D heterobimetallic Ca–Ag coordination polymer (CP) [Ca(DMF)4Ag2(SCN)4]n (1) (DMF = N,N-dimethylformamide). 1 is constructed by Ca metallic atoms, Ag2 dinuclear cluster, and SCN− bridges. This Ca–Ag CP exhibits strong luminescence property in its DMF suspension, and has been exploited as a highly sensitive sensor for the detection of TNP. Moreover, the energy-transfer mechanism of 1 for sensing TNP had been preliminarily elucidated.
Publisher URL: https://link.springer.com/article/10.1007/s10876-018-1344-z
DOI: 10.1007/s10876-018-1344-z
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