ACS Applied Materials & Interfaces
ACS Applied Materials & Interfaces
3 years ago

Cross Stacking of Nanopatterned PEDOT Films for Use as Soft Electrodes

Cross Stacking of Nanopatterned PEDOT Films for Use as Soft Electrodes
Jongbeom Na, Eunkyoung Kim, Chihyun Park
Cross stacking of nanopatterned conductive polymer film was explored using a sacrificial soft template made of nanopatterned polystyrene (PS) film as a guide for nanopatterned conductive polymer film. For use as a conductive film, the PS pattern was filled with poly(3,4-ethylenedioxythiophene) (PEDOT), and then completely removed, to generate single-patterned PEDOT (SPDOT) film having a conductivity of 1079 S/cm, which was comparable to the pristine unpatterned PEDOT (UPDOT) film on a glass slide. SPDOT layers were stacked across each other to form double-layered (DPDOT) and multiple-layered patterned PEDOT film on a glass slide or polymeric substrate. The patterned PEDOT film showed enhanced optical and electrochemical activity; specifically as compared to the UPDOT film on a glass slide, the DPDOT film showed an increase in reflectance and an enhanced electrochemically active surface by 23.4% and 32.8%, respectively. The patterned PEDOT film on a polymer substrate showed high bendability up to being completely folded and maintained its conductivity for over 10 000 cycles of bending. The patterned PEDOT layers were applied to dye-sensitized solar cells (DSSCs) as a transparent conductive oxide (TCO)-free counter electrode. An N719-based DSSC with a DPDOT film recorded a photoconversion efficiency of 7.54%, which is one of the highest values among the TCO-free DSSCs based on a PEDOT counter electrode.

Publisher URL: http://dx.doi.org/10.1021/acsami.7b07799

DOI: 10.1021/acsami.7b07799

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