Inorganic Chemistry
Inorganic Chemistry
5 years ago

New Titanium Borylimido Compounds: Synthesis, Structure, and Bonding

New Titanium Borylimido Compounds: Synthesis, Structure, and Bonding
Martin Slusarczyk, Simona Mellino, Benjamin A. Clough, Philip Mountford, Eric Clot, Matthew P. Blake, Bowen Xie, Laura C. Stevenson, Andrey V. Protchenko
Very few borylimides (M = NBR2) have previously been reported, all by diverse routes. Here we present a combined experimental and computational study of titanium borylimides. Their electronic structures, bond energies, and imide-amine exchange reactions have been evaluated using density functional theory, quantum theory of atoms in molecules, and natural bond orbital analysis. These features are placed more generally in context with the corresponding alkyl- and arylimides and hydrazides.

Publisher URL: http://dx.doi.org/10.1021/acs.inorgchem.7b01831

DOI: 10.1021/acs.inorgchem.7b01831

You might also like
Discover & Discuss Important Research

Keeping up-to-date with research can feel impossible, with papers being published faster than you'll ever be able to read them. That's where Researcher comes in: we're simplifying discovery and making important discussions happen. With over 19,000 sources, including peer-reviewed journals, preprints, blogs, universities, podcasts and Live events across 10 research areas, you'll never miss what's important to you. It's like social media, but better. Oh, and we should mention - it's free.

  • Download from Google Play
  • Download from App Store
  • Download from AppInChina

Researcher displays publicly available abstracts and doesn’t host any full article content. If the content is open access, we will direct clicks from the abstracts to the publisher website and display the PDF copy on our platform. Clicks to view the full text will be directed to the publisher website, where only users with subscriptions or access through their institution are able to view the full article.