Inorganic Chemistry
Inorganic Chemistry
5 years ago

Facile and Efficient Decontamination of Thorium from Rare Earths Based on Selective Selenite Crystallization

Facile and Efficient Decontamination of Thorium from Rare Earths Based on Selective Selenite Crystallization
Juan Diwu, Lanhua Chen, Huangjie Lu, Yaxing Wang, Zhifang Chai, Yawen Cai, Xing Dai, Shiyu Du, Xuemiao Yin, Ruhong Zhou, Xiaojing Bai, Shuao Wang, Ning Liu, Thomas E. Albrecht-Schmitt, Tao Duan
A unique selective crystallization system where tetravalent f elements Ce and Th are exclusively trapped into the crystal, significantly precluding incorporation of trivalent rare earth elements. This process further gives rise to a highly efficient and environmental friendly strategy for the decontamination of thorium from REE ores.

Publisher URL: http://dx.doi.org/10.1021/acs.inorgchem.7b02681

DOI: 10.1021/acs.inorgchem.7b02681

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