5 years ago

Synthesis and Structure of N,N-Dinitroamidoborane Complexes

Synthesis and Structure of N,N-Dinitroamidoborane Complexes
Alexey Yu. Sukhorukov, Vladimir A. Tartakovsky, Oleg P. Shitov, Sema L. Ioffe, Ivan S. Golovanov
Boranes with a bang! Combining reducing and oxidizing fragments in a single covalently bonded structure is an attractive strategy for the construction of high-energy materials. In this work, the syntheses of a series of unusual boranes, bearing one or two dinitroamide fragments at the boron atom, are reported. Ab initio calculations and experimental data suggest that these boranes exist in two slowly interconvertible isomeric forms (B,N- and B,O-linked) that may have distinct explosive characteristics. More information can be found in the Full Paper by Alexey Yu. Sukhorukov, Sema L Ioffe et al. (DOI: 10.1002/asia.201700603).

Publisher URL: http://onlinelibrary.wiley.com/resolve/doi

DOI: 10.1002/asia.201701103

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