3 years ago

Porphyrins Sheathed in Quadrupolar Solvation Spheres of Hexafluorobenzene: Solvation-Induced Fluorescence Enhancement and Conformational Confinement

Porphyrins Sheathed in Quadrupolar Solvation Spheres of Hexafluorobenzene: Solvation-Induced Fluorescence Enhancement and Conformational Confinement
Noriaki Ikeda, Ikuya Ueno, Masaki Shimizu, Mitsuhiko Morisue, Takashi Yumura
Hexafluorobenzene (C6F6) strongly solvated the porphyrin ring via a quadrupolar interaction. The solvation sphere of C6F6 hindered the thermal fluctuations near the porphyrin ring and evoked remarkable photoelectronic properties of the porphyrins such as fluorescence enhancement and spectral sharpening due to confined torsional planarity.

Publisher URL: http://dx.doi.org/10.1021/acs.jpcc.7b04083

DOI: 10.1021/acs.jpcc.7b04083

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