Industrial & Engineering Chemistry Research
Industrial & Engineering Chemistry Research
5 years ago

Insight into Influence of Glycerol on Preparing α-CaSO4·1/2H2O from Flue Gas Desulfurization Gypsum in Glycerol–Water Solutions with Succinic Acid and NaCl

Insight into Influence of Glycerol on Preparing α-CaSO4·1/2H2O from Flue Gas Desulfurization Gypsum in Glycerol–Water Solutions with Succinic Acid and NaCl
Yuehua Hu, Qingjun Guan, Wei Sun, Honghu Tang, Zhigang Yin
The conversion of CaSO4·2H2O (DH) to CaSO4·1/2H2O (HH) was facilitated by increasing glycerol content from 55% to 85% in glycerol–water mixtures; the average length and diameter of produced α-HH crystals decreased from 60.97 to 7.21 μm and from 15.21 to 5.17 μm, respectively, resulting in a decrease in the average aspect ratio from 4.06 to 1.41. The phase transformation was reduced dramatically from 30 to 3 h. As glycerol content increased in the mixtures, an increase in α-HH maximal relative supersaturation and decrease of ion diffusion rate were hypothesized as explanations for the morphology change in the alpha-hemihydrate (α-HH) produced. The kinematic feasibility of FGD gypsum transition to α-HH in the mixed solutions with the increase of glycerol should also be attributed to the enhancement of maximal relative supersaturation for α-HH precipitation.

Publisher URL: http://dx.doi.org/10.1021/acs.iecr.7b02067

DOI: 10.1021/acs.iecr.7b02067

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