Inorganic Chemistry
Inorganic Chemistry
5 years ago

Synthetic, Structural, and Spectroscopic Characterization of a Novel Family of High-Spin Iron(II) [(β-Diketiminate)(phosphanylphosphido)] Complexes

Synthetic, Structural, and Spectroscopic Characterization of a Novel Family of High-Spin Iron(II) [(β-Diketiminate)(phosphanylphosphido)] Complexes
Sebastian A. Stoian, Łukasz Ponikiewski, Rafał Grubba, Jerzy Pikies, Wiesława Ferenc, Alina Dragulescu-Andrasi, Beata Cristóvão, J. Krzystek, Kinga Kaniewska
The synthesis of a new class of iron(II) complexes with diphosphorous ligands was presented. Solid-state structures of these complexes were established by single-crystal X-ray diffraction. Moreover, the ground-state magnetic properties of these new low-coordinate iron(II) complexes were assessed by analyzing the magnetic susceptibility and field- and temperature-dependent 57Fe Mössbauer spectra in the framework of a standard S = 2 spin-Hamiltonian model.

Publisher URL: http://dx.doi.org/10.1021/acs.inorgchem.7b01374

DOI: 10.1021/acs.inorgchem.7b01374

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