5 years ago

Mobility Gradient of Poly(ethylene terephthalate) Chains near a Substrate Scaled by the Thickness of the Adsorbed Layer

Mobility Gradient of Poly(ethylene terephthalate) Chains near a Substrate Scaled by the Thickness of the Adsorbed Layer
Juping Yang, Yang Lan, Biao Zuo, Zhenshan Liu, Wei Zhang, Xinping Wang, Wenbing Hu, Jianquan Xu
The question of how to scale the mobility gradient of polymer chains near a substrate in supported ultrathin polymer films is a great challenge. In this paper, a mobility gradient of poly(ethylene terephthalate) (PET) chains near a substrate is characterized by cold crystallization. We found that either decreasing the PET film thickness or increasing the absorbed layer thickness consistently reveals three characteristic film thicknesses, which are all linearly dependent on the adsorbed-layer thickness. At the first thickness, the low-temperature peak of the top surface crystallization starts to shift toward the high-temperature peak of the bulk-like polymer crystallization; at the second thickness, it arrives there; and at the third thickness, crystallization is completely suppressed. The three kinds of film thicknesses characterize the depth profile of the local dynamics, reflecting the long-range effects of the substrate, which could be scaled by the thickness of the adsorbed layer.

Publisher URL: http://dx.doi.org/10.1021/acs.macromol.7b00922

DOI: 10.1021/acs.macromol.7b00922

You might also like
Discover & Discuss Important Research

Keeping up-to-date with research can feel impossible, with papers being published faster than you'll ever be able to read them. That's where Researcher comes in: we're simplifying discovery and making important discussions happen. With over 19,000 sources, including peer-reviewed journals, preprints, blogs, universities, podcasts and Live events across 10 research areas, you'll never miss what's important to you. It's like social media, but better. Oh, and we should mention - it's free.

  • Download from Google Play
  • Download from App Store
  • Download from AppInChina

Researcher displays publicly available abstracts and doesn’t host any full article content. If the content is open access, we will direct clicks from the abstracts to the publisher website and display the PDF copy on our platform. Clicks to view the full text will be directed to the publisher website, where only users with subscriptions or access through their institution are able to view the full article.