Journal of the American Chemical Society
Journal of the American Chemical Society
5 years ago

Site-Selective Catalytic Carboxylation of Unsaturated Hydrocarbons with CO2 and Water

Site-Selective Catalytic Carboxylation of Unsaturated Hydrocarbons with CO2 and Water
Toni Moragas, Morgane Gaydou, Francisco Juliá-Hernández, Ruben Martin
A catalytic protocol that reliably predicts and controls the site-selective incorporation of CO2 to a wide range of unsaturated hydrocarbons utilizing water as formal hydride source is described. This platform unlocks an opportunity to catalytically repurpose three abundant, orthogonal feedstocks under mild conditions.

Publisher URL: http://dx.doi.org/10.1021/jacs.7b07637

DOI: 10.1021/jacs.7b07637

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