Chemistry - A European Journal
Chemistry - A European Journal
5 years ago

The Interaction Modes of Haloimidazolium Salts in Solution

The Interaction Modes of Haloimidazolium Salts in Solution
Nils Schulz, Stefan M. Huber, Mate Erdelyi, Elric Engelage, Pandian Sokkar, Elsa Sanchez-Garcia, Severin Schindler
Haloimidazolium salts have gained importance as halogen-bond donors—halogen-based Lewis acids—in many applications including anion recognition and organocatalysis. However, little is known so far about their binding mode to anions in solution, as they could interact with Lewis bases via halogen bonding, hydrogen bonding, or anion–π interactions. In this study, this issue is addressed by a variety of techniques including calorimetry, NMR spectroscopy, and quantum-chemical calculations. More information can be found in the Full Paper by E. Sanchez-Garcia, S. M. Huber, et al. (DOI: 10.1002/chem.201705032).

Publisher URL: http://onlinelibrary.wiley.com/resolve/doi

DOI: 10.1002/chem.201800256

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