Crystal Growth & Design
Crystal Growth & Design
5 years ago

Homochiral Coordination Polymers Based on Amino Acid-Functionalized Isophthalic Acid: Synthesis, Structure Determination, and Optical Properties

Homochiral Coordination Polymers Based on Amino Acid-Functionalized Isophthalic Acid: Synthesis, Structure Determination, and Optical Properties
Benlai Wu, Keqing Zhang, Rui Chen, Xing Wang, Wenbo Wang, Lulu Lv
Three two-/three-dimensional homochiral metal−organic frameworks with unique architectures and interesting topologies were synthesized and characterized by elemental analysis, TGA, spectroscopic methods, and X-ray diffraction analysis. More importantly, the coordination mode, hydrogen-bonding site, existence form, and charge of the amino acid-functionalized polycarboxylate chiral ligand can be controlled by the protonation of its amino group, which results in the structural diversity.

Publisher URL: http://dx.doi.org/10.1021/acs.cgd.7b01689

DOI: 10.1021/acs.cgd.7b01689

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