Inorganic Chemistry
Inorganic Chemistry
5 years ago

E–H Bond Activation and Insertion Processes in the Reactions of the Unsaturated Hydride [W2Cp2(μ-H)(μ-PPh2)(NO)2]

E–H Bond Activation and Insertion Processes in the Reactions of the Unsaturated Hydride [W2Cp2(μ-H)(μ-PPh2)(NO)2]
Adrián Toyos, Daniel García-Vivó, Miguel A. Ruiz, M. Angeles Alvarez, M. Esther García
Different p-block-element (E) molecules having E−H bonds, or C−N multiple bonds, readily add to the title complex under mild conditions, but this is invariably followed by additional processes, including E−H bond cleavage, dehydrogenation, insertion, and denitrogenation, to give a plethora of derivatives having different ligands bridging the tungsten atoms.

Publisher URL: http://dx.doi.org/10.1021/acs.inorgchem.7b03111

DOI: 10.1021/acs.inorgchem.7b03111

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