Inorganic Chemistry
Inorganic Chemistry
5 years ago

A Dense I1O3 Hybrid Superhydrophobic Network, Pb(H-BTMB), Exhibits Selectivity toward CO2 Gas Sorption

A Dense I1O3 Hybrid Superhydrophobic Network, Pb(H-BTMB), Exhibits Selectivity toward CO2 Gas Sorption
Yerraguntla Katyayani Devi, Jettiboina Suryachandram, Koya Prabhakara Rao, J. N. Behera, Rayavarapu Prasada Rao
A dense I1O3 hybrid porous coordination polymer (PCP), [Pb(H-BTMB)(DMF)], with open metal sites (OMSs) has been synthesized. It has a three-dimensional structure with micropores exhibiting selective adsorption toward CO2 gas over various other gas molecules such as N2, CH4, and C2H6. Moreover, it has a stable superhydrophobic surface even at high temperatures, with a contact angle of 156.4°.

Publisher URL: http://dx.doi.org/10.1021/acs.inorgchem.7b01551

DOI: 10.1021/acs.inorgchem.7b01551

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