Inorganic Chemistry
Inorganic Chemistry
5 years ago

Novel Three-Dimensional Semiconducting Materials Based on Hybrid d10 Transition Metal Halogenides as Visible Light-Driven Photocatalysts

Novel Three-Dimensional Semiconducting Materials Based on Hybrid d10 Transition Metal Halogenides as Visible Light-Driven Photocatalysts
Cheng-Yang Yue, Yan Li, Bing Hu, Fu-Qi Mi, Rui-Qing Li, Chun-Lei Wang, Hui Gao, Na Lin, Fan Wu, Xiao-Wu Lei
We developed the first examples of inorganic−organic hybrid cuprous and silver halogenides of the type [(Me)2-2,2′-bipy]M8X10 (M = Cu or Ag; X = Br or I) with novel three-dimensional networks and stable visible light-driven photocatalytic properties due to the template effects, band structural regulation, and separating abilities of photoinduced carriers originating from the photosensitive cations.

Publisher URL: http://dx.doi.org/10.1021/acs.inorgchem.7b01171

DOI: 10.1021/acs.inorgchem.7b01171

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