3 years ago

Direct Kinetic Evidence for the Active Anionic Palladium(0) and Palladium(II) Intermediates in the Ligand-Free Heck Reaction with Aromatic Carboxylic Anhydrides

Direct Kinetic Evidence for the Active Anionic Palladium(0) and Palladium(II) Intermediates in the Ligand-Free Heck Reaction with Aromatic Carboxylic Anhydrides
Elizaveta V. Larina, Nadezhda A. Lagoda, Anna A. Kurokhtina, Elena V. Yarosh, Alexander F. Schmidt
Differential selectivity in the competitive Heck reaction with aromatic carboxylic anhydrides has been found to depend on the nature of both the cation and anion of a salt used as an additive for the catalytic system. This fact indicates that the anions present in the system are involved in active anionic species.

Publisher URL: http://dx.doi.org/10.1021/acs.organomet.7b00496

DOI: 10.1021/acs.organomet.7b00496

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