Inorganic Chemistry
Inorganic Chemistry
5 years ago

Triazolylidene Iridium Complexes for Highly Efficient and Versatile Transfer Hydrogenation of CO, CN, and CC Bonds and for Acceptorless Alcohol Oxidation

Triazolylidene Iridium Complexes for Highly Efficient and Versatile Transfer Hydrogenation of CO, CN, and CC Bonds and for Acceptorless Alcohol Oxidation
Zahra Mazloomi, René Pretorius, Montserrat Diéguez, Martin Albrecht, Oscar Pàmies
New complexes containing iridium triazolylidenes for the highly efficient and versatile transfer hydrogenation of C═O, C═N, and C═C bonds and for alcohol dehydrogenation are reported. A set of mechanistic studies has identified distinct rate-determining steps for transfer hydrogenation and for acceptorless alcohol oxidation. These results underline the relevance of ligand design principles, and they provide guidelines for further optimization and for the design of new efficient systems.

Publisher URL: http://dx.doi.org/10.1021/acs.inorgchem.7b01707

DOI: 10.1021/acs.inorgchem.7b01707

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