Assembly of a Two-Fold Interpenetrated Three-Dimensional Metal–Organic Framework by Using the Template Function of Keggin Anions
Abstract
A metal–organic framework [Co2(btp)3(GeMo12O40)] (1) (btp = 1,3-bis-(1,2,4-triazol-1-yl)propane) has been constructed by using the template function of the Keggin anions GeMo12O404−. Single-crystal X-ray analysis reveals that the structure exhibits two-fold interpenetrated 3D host metal–organic framework constructed from cobalt(II) and btp linkers and the voids of which are occupied by Keggin anions. The optical band gap of 1 indicates that it is potential wide-gap semiconductive material. The photocatalytic activity of compound 1 in degradation of MB under visible light and UV light irradiation are also investigated.
Publisher URL: https://link.springer.com/article/10.1007/s10876-018-1347-9
DOI: 10.1007/s10876-018-1347-9
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