Axial Ligand Field in D4d Coordination Symmetry: Magnetic Relaxation of Dy SMMs Perturbed by Counteranions

5 years ago

Axial Ligand Field in D4d Coordination Symmetry: Magnetic Relaxation of Dy SMMs Perturbed by Counteranions

Lang Zhao, Boris Le Guennic, Xiao-Lei Li, Olivier Cador, Jinkui Tang, Jianfeng Wu

An axial ligand field with short Dy−O_sali distance and less π−π stacking is found in closely related dysprosium compounds with discriminative counteranions, where the metal in a square-antiprismatic geometry suppresses quantum tunneling and enhances the magnetic relaxation.

Publisher URL: http://dx.doi.org/10.1021/acs.inorgchem.7b01582

DOI: 10.1021/acs.inorgchem.7b01582

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