5 years ago

Palladium-Catalyzed Intermolecular Exchange between C–C and C–Si σ-Bonds

Palladium-Catalyzed Intermolecular Exchange between C–C and C–Si σ-Bonds
Fangzhu Sun, Masahiro Murakami, Naoki Ishida, Shintaro Okumura
A palladium–isocyanide complex opens the two four-membered rings of benzocyclobutenone and silacyclobutane to merge them into an eight-membered ring skeleton. The present reaction provides a unique example of an intermolecular cross metathesis-type reaction between covalent σ-bonds of low polarity.

Publisher URL: http://dx.doi.org/10.1021/jacs.7b07667

DOI: 10.1021/jacs.7b07667

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