3 years ago

Organoselenium-Catalyzed Oxidative CC Bond Cleavage: A Relatively Green Oxidation of Alkenes into Carbonyl Compounds with Hydrogen Peroxide

Organoselenium-Catalyzed Oxidative CC Bond Cleavage: A Relatively Green Oxidation of Alkenes into Carbonyl Compounds with Hydrogen Peroxide
Chao Chen, Lei Yu, Xiaobi Jing, Tingting Wang
A relatively green oxidative C═C bond cleavage of alkenes was achieved by organoselenium-catalyzed alkene oxidation reaction in ethanol with hydrogen peroxide, affording carbonyl compounds under relatively mild conditions. It is a new reaction style for the organoselenium-catalyzed oxidation of alkenes and largely contributes to the growing field of organoselenium catalysis.

Publisher URL: http://dx.doi.org/10.1021/acs.joc.7b01245

DOI: 10.1021/acs.joc.7b01245

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