Rhodium(III)-Catalyzed C–H Activation of Nitrones and Annulative Coupling with Nitroalkenes

5 years ago

Rhodium(III)-Catalyzed C–H Activation of Nitrones and Annulative Coupling with Nitroalkenes

Fen Wu, Xingwei Li, Junbiao Chang, Dachang Bai, Bingxian Liu, Qingqian Jia, Teng Xu, Chaorui Ma, Qiuqiu Zhang

Rh(III)-catalyzed synthesis of nitro-functionalized indenes has been realized via C–H activation of arylnitrones and annulation with nitroolefins. The reaction proceeded in moderate to high yields with good functional group tolerance under ambient atmosphere.

Publisher URL: http://dx.doi.org/10.1021/acs.joc.7b01574

DOI: 10.1021/acs.joc.7b01574

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