Inorganic Chemistry
Inorganic Chemistry
5 years ago

Visible-Light-Driven Photosystems Using Heteroleptic Cu(I) Photosensitizers and Rh(III) Catalysts To Produce H2

Visible-Light-Driven Photosystems Using Heteroleptic Cu(I) Photosensitizers and Rh(III) Catalysts To Produce H2
Allen J. Osinski, Bradley J. McCullough, Bertrand J. Neyhouse, Demi T. Reed, Christopher J. Ziegler, Briana R. Schrage, Travis A. White
Two new heteroleptic Cu(I) photosensitizers undergo reductive quenching upon visible light excitation in the presence of a sacrificial electron donor. Subsequent intermolecular electron transfer to the Rh(III) water reduction catalysts and H2 evolution is strongly affected by the π-accepting diimine ligand within the Cu(I) architecture, illustrating the importance of appropriate structural design considerations.

Publisher URL: http://dx.doi.org/10.1021/acs.inorgchem.7b03273

DOI: 10.1021/acs.inorgchem.7b03273

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