Inorganic Chemistry
Inorganic Chemistry
5 years ago

Preparation, Structure Evolution, and Metal–Insulator Transition of NaxRhO2 Crystals (0.25 ≤ x ≤ 1)

Preparation, Structure Evolution, and Metal–Insulator Transition of NaxRhO2 Crystals (0.25 ≤ x ≤ 1)
Lunyong Zhang, Bin-Bin Zhang, Yadong Xu, Cong Wang, Jian Zhou, Yang-Yang Lv, Yan-Feng Chen, Shu-Hua Yao, Song-Tao Dong, Y. B. Chen
The crystal growth of NaRhO2 crystals by a modified vapor transport method and a series of NaxRhO2 (x = 0.25−0.91) crystals through desodiation chemical method are shown. An insulator−metal transition was observed in NaxRhO2, which is strongly dependent on x. The conducting mechanism is correlated to carrier density as well as to a chemical bonding change.

Publisher URL: http://dx.doi.org/10.1021/acs.inorgchem.7b03110

DOI: 10.1021/acs.inorgchem.7b03110

You might also like
Discover & Discuss Important Research

Keeping up-to-date with research can feel impossible, with papers being published faster than you'll ever be able to read them. That's where Researcher comes in: we're simplifying discovery and making important discussions happen. With over 19,000 sources, including peer-reviewed journals, preprints, blogs, universities, podcasts and Live events across 10 research areas, you'll never miss what's important to you. It's like social media, but better. Oh, and we should mention - it's free.

  • Download from Google Play
  • Download from App Store
  • Download from AppInChina

Researcher displays publicly available abstracts and doesn’t host any full article content. If the content is open access, we will direct clicks from the abstracts to the publisher website and display the PDF copy on our platform. Clicks to view the full text will be directed to the publisher website, where only users with subscriptions or access through their institution are able to view the full article.