Inorganic Chemistry
Inorganic Chemistry
5 years ago

Structural and Chemical Effects of the PtBu2 Bridge at Unsaturated Dimolybdenum Complexes Having Hydride and Hydrocarbyl Ligands

Structural and Chemical Effects of the PtBu2 Bridge at Unsaturated Dimolybdenum Complexes Having Hydride and Hydrocarbyl Ligands
Melodie Casado-Ruano, M. Angeles Alvarez, Daniel García-Vivó, M. Esther García, Miguel A. Ruiz
We present a high yield route for the preparation of the 30-electron anion [Mo2Cp2(μ-PtBu2)(μ-CO)2]− having a bulky PtBu2-bridge. This anion is a key entry point into the chemistry of different unsaturated hydride and hydrocarbyl complexes stabilized by this bulky bridging group, which also has significant effects on the structure and chemical behavior of these species.

Publisher URL: http://dx.doi.org/10.1021/acs.inorgchem.7b01773

DOI: 10.1021/acs.inorgchem.7b01773

You might also like
Discover & Discuss Important Research

Keeping up-to-date with research can feel impossible, with papers being published faster than you'll ever be able to read them. That's where Researcher comes in: we're simplifying discovery and making important discussions happen. With over 19,000 sources, including peer-reviewed journals, preprints, blogs, universities, podcasts and Live events across 10 research areas, you'll never miss what's important to you. It's like social media, but better. Oh, and we should mention - it's free.

  • Download from Google Play
  • Download from App Store
  • Download from AppInChina

Researcher displays publicly available abstracts and doesn’t host any full article content. If the content is open access, we will direct clicks from the abstracts to the publisher website and display the PDF copy on our platform. Clicks to view the full text will be directed to the publisher website, where only users with subscriptions or access through their institution are able to view the full article.