3 years ago

Combining the catalytic enantioselective reaction of visible-light-generated radicals with a by-product utilization system

Combining the catalytic enantioselective reaction of visible-light-generated radicals with a by-product utilization system
Olaf Burghaus, Richard D. Webster, Xiaoqiang Huang, Eric Meggers, Klaus Harms, Shipeng Luo
We report an unusual reaction design in which a chiral bis-cyclometalated rhodium(III) complex enables the stereocontrolled chemistry of photo-generated carbon-centered radicals and at the same time catalyzes an enantioselective sulfonyl radical addition to an alkene.

Publisher URL: http://feeds.rsc.org/~r/rss/SC/~3/cE2cp8xagh4/C7SC02621H

DOI: 2017/SC/C7SC02621H

You might also like
Discover & Discuss Important Research

Keeping up-to-date with research can feel impossible, with papers being published faster than you'll ever be able to read them. That's where Researcher comes in: we're simplifying discovery and making important discussions happen. With over 19,000 sources, including peer-reviewed journals, preprints, blogs, universities, podcasts and Live events across 10 research areas, you'll never miss what's important to you. It's like social media, but better. Oh, and we should mention - it's free.

  • Download from Google Play
  • Download from App Store
  • Download from AppInChina

Researcher displays publicly available abstracts and doesn’t host any full article content. If the content is open access, we will direct clicks from the abstracts to the publisher website and display the PDF copy on our platform. Clicks to view the full text will be directed to the publisher website, where only users with subscriptions or access through their institution are able to view the full article.