Chemical Science
Chemical Science
5 years ago

Combining the catalytic enantioselective reaction of visible-light-generated radicals with a by-product utilization system

Combining the catalytic enantioselective reaction of visible-light-generated radicals with a by-product utilization system
Olaf Burghaus, Richard D. Webster, Xiaoqiang Huang, Eric Meggers, Klaus Harms, Shipeng Luo
We report an unusual reaction design in which a chiral bis-cyclometalated rhodium(III) complex enables the stereocontrolled chemistry of photo-generated carbon-centered radicals and at the same time catalyzes an enantioselective sulfonyl radical addition to an alkene.

Publisher URL: http://feeds.rsc.org/~r/rss/SC/~3/cE2cp8xagh4/C7SC02621H

DOI: 2017/SC/C7SC02621H

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