Chemistry - A European Journal
Chemistry - A European Journal
5 years ago

Bis(6-methylene-2,2‘-bipyridine)phenylphosphine—A Flexible Ligand for the Construction of Trinuclear Coinage-Metal Complexes

Bis(6-methylene-2,2‘-bipyridine)phenylphosphine—A Flexible Ligand for the Construction of Trinuclear Coinage-Metal Complexes
Sebastian Schäfer, Michael T. Gamer, Florian Weigend, Manfred M. Kappes, Sergei Lebedkin, Peter W. Roesky
A tailor-made ligand with different metal binding sites was introduced to the coordination chemistry of the coinage metals. As a result of the different metal binding sites (bipyridine vs. phosphine), two different coinage metals can be selectively anchored into the coordination compartments. Investigation of the photophysical properties in the solid state revealed different behavior between Au-Cu, Au-Ag, and Ag-Ag compounds. The picture shows all three coinage metals, the corresponding {AuCu2} and {AuAg2} complexes, as well as some photoluminescence spectra of the reported complexes. More information can be found in the Full Paper by P. W. Roesky et al. (DOI: 10.1002/chem.201701091).

Publisher URL: http://onlinelibrary.wiley.com/resolve/doi

DOI: 10.1002/chem.201702136

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