4 years ago

Phototriggered Dehydration Condensation Using an Aminocyclopropenone

Phototriggered Dehydration Condensation Using an Aminocyclopropenone
Yuki Yushima, Munetaka Kunishima, Kenji Mishiro
A phototriggered dehydration condensation using an aminocyclopropenone has been developed. The UV irradiation of an aminocyclopropenone generated a highly reactive ynamine in situ and the dehydration condensation of a carboxylic acid and an amine coexisting in the reaction solution smoothly proceeded to afford an amide. This reaction is completely controllable by the ON/OFF states of a UV lamp.

Publisher URL: http://dx.doi.org/10.1021/acs.orglett.7b02383

DOI: 10.1021/acs.orglett.7b02383

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