Crystal Growth & Design
Crystal Growth & Design
5 years ago

Construction of (3,4)-Connected Polyoxometalate-Based Metal–Organic Frameworks (POMOFs) from Triangular Carboxylate and Tetrahedral Zn4-ε-Keggin

Construction of (3,4)-Connected Polyoxometalate-Based Metal–Organic Frameworks (POMOFs) from Triangular Carboxylate and Tetrahedral Zn4-ε-Keggin
Bao-Xia Dong, Yun-Lei Teng, Yi-Chen Wu, Zong-Wei Li, Fan-Yan Bu, Wen-Long Liu, Juan Zhao
By virtue of a 3,5′,3″-substituted terphenyl-based tricarboxylate H3L1, a polyoxometalate-based metal−organic framework of YZU-103 was constructed, which exhibits an unprecedented (3,4)-connected (6·84·10)3(62·8)4 topology (labeled as yzu) on the basis of tetrahedral {Zn4-ε-Keggin} building block. To date, only three types of topologies of ctn, bor, and ofp were identified for the (3,4)-connected nets.

Publisher URL: http://dx.doi.org/10.1021/acs.cgd.7b00825

DOI: 10.1021/acs.cgd.7b00825

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