4 years ago

Syntheses and Properties of Gold–Organotin Sulfide Clusters

Syntheses and Properties of Gold–Organotin Sulfide Clusters
Sangam Chatterjee, Nils W. Rosemann, Eike Dornsiepen, Stefanie Dehnen, Jens P. Eußner
Ternary gold−organotin phosphane complexes, [(R1Sn)2(AuPMe3)2S4] (1) and [(R2Sn)2(AuPMe3)2S4] [2; R2 = CMe2CH2C(NNH2)Me], were synthesized, and their electronic properties were studied by means of density functional theory calculations and spectroscopy. A third compound comprises a binary tin sulfide cluster that cocrystallizes with a structure-directing salt of a gold phosphane complex, [Au(dppe)2][(R3Sn)4S6Cl] [3; R3 = CMe2CH2C(NNHPh)Me].

Publisher URL: http://dx.doi.org/10.1021/acs.inorgchem.7b01713

DOI: 10.1021/acs.inorgchem.7b01713

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