Inorganic Chemistry
Inorganic Chemistry
5 years ago

Enantioselective Aldol Reactions in Water by a Proline-Derived Cryptand and Fixation of CO2 by Its Exocyclic Co(II) Complex

Enantioselective Aldol Reactions in Water by a Proline-Derived Cryptand and Fixation of CO2 by Its Exocyclic Co(II) Complex
Parimal K. Bharadwaj, Aditya Bhattacharyya, Dinesh De
l-Proline functionalized chiral cryptand L efficiently catalyzed the aldol reactions in water. The Co(II) complex 1 in combination with TBAB catalyzed the cycloaddition of epoxides and CO2 under ambient conditions affording the cyclic carbonates.

Publisher URL: http://dx.doi.org/10.1021/acs.inorgchem.7b02007

DOI: 10.1021/acs.inorgchem.7b02007

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