Advanced Materials
Advanced Materials
5 years ago

High-Energy/Power and Low-Temperature Cathode for Sodium-Ion Batteries: In Situ XRD Study and Superior Full-Cell Performance

High-Energy/Power and Low-Temperature Cathode for Sodium-Ion Batteries: In Situ XRD Study and Superior Full-Cell Performance
Yu-Guo Guo, Qingyu Yan, Xing-Long Wu, Jin-Zhi Guo, Peng-Fei Wang, Jing-Ping Zhang, Hong Chen, Xiao-Hua Zhang
Sodium-ion batteries (SIBs) are still confronted with several major challenges, including low energy and power densities, short-term cycle life, and poor low-temperature performance, which severely hinder their practical applications. Here, a high-voltage cathode composed of Na3V2(PO4)2O2F nano-tetraprisms (NVPF-NTP) is proposed to enhance the energy density of SIBs. The prepared NVPF-NTP exhibits two high working plateaux at about 4.01 and 3.60 V versus the Na+/Na with a specific capacity of 127.8 mA h g−1. The energy density of NVPF-NTP reaches up to 486 W h kg−1, which is higher than the majority of other cathode materials previously reported for SIBs. Moreover, due to the low strain (≈2.56% volumetric variation) and superior Na transport kinetics in Na intercalation/extraction processes, as demonstrated by in situ X-ray diffraction, galvanostatic intermittent titration technique, and cyclic voltammetry at varied scan rates, the NVPF-NTP shows long-term cycle life, superior low-temperature performance, and outstanding high-rate capabilities. The comparison of Ragone plots further discloses that NVPF-NTP presents the best power performance among the state-of-the-art cathode materials for SIBs. More importantly, when coupled with an Sb-based anode, the fabricated sodium-ion full-cells also exhibit excellent rate and cycling performances, thus providing a preview of their practical application. A high-voltage sodium-super-ion-conductor-type cathode significantly enhances the energy density of sodium-ion batteries. Its low-strain crystal lattice during the successive (de-)sodiation and superior Na transport kinetics promise high-rate capabilities, long-term cycle life, superior low-temperature performance, and excellent full-cell performance, providing a preview of their practical applications.

Publisher URL: http://onlinelibrary.wiley.com/resolve/doi

DOI: 10.1002/adma.201701968

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