Advanced Materials
Advanced Materials
5 years ago

Polymer:Fullerene Bimolecular Crystals for Near-Infrared Spectroscopic Photodetectors

Polymer:Fullerene Bimolecular Crystals for Near-Infrared Spectroscopic Photodetectors
Andreas Mischok, Yuan Liu, Sascha Ullbrich, Koen Vandewal, Weiwei Li, Zheng Tang, Mariano Campoy-Quiles, Antonio Sánchez-Díaz, Zaifei Ma, Karl Leo, Bernhard Siegmund
Spectroscopic photodetection is a powerful tool in disciplines such as medical diagnosis, industrial process monitoring, or agriculture. However, its application in novel fields, including wearable and biointegrated electronics, is hampered by the use of bulky dispersive optics. Here, solution-processed organic donor–acceptor blends are employed in a resonant optical cavity device architecture for wavelength-tunable photodetection. While conventional photodetectors respond to above-gap excitation, the cavity device exploits weak subgap absorption of intermolecular charge-transfer states of the intercalating poly[2,5-bis(3-tetradecylthiophen-2-yl)thieno[3,2-b]thiophene] (PBTTT):[6,6]-phenyl-C61-butyric acid methyl ester (PCBM) bimolecular crystal. This enables a highly wavelength selective, near-infrared photoresponse with a spectral resolution down to 14 nm, as well as dark currents and detectivities comparable with commercial inorganic photodetectors. Based on this concept, a miniaturized spectrophotometer, comprising an array of narrowband cavity photodetectors, is fabricated by using a blade-coated PBTTT:PCBM thin film with a thickness gradient. As an application example, a measurement of the transmittance spectrum of water by this device is demonstrated. Solution-processed organic donor–acceptor blends are employed in a resonant optical cavity device architecture, providing tunable and narrowband photodetectors and miniature spectrometers. While conventional photodetectors respond to above-gap excitation, these cavity devices exploit weak subgap absorption of intermolecular charge-transfer states of intercalating bimolecular crystals.

Publisher URL: http://onlinelibrary.wiley.com/resolve/doi

DOI: 10.1002/adma.201702184

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