3 years ago

Frontispiece: Molecular Assemblies of Metal Complexes via Base-Pairing of Nucleic Acids in the Crystalline State

Frontispiece: Molecular Assemblies of Metal Complexes via Base-Pairing of Nucleic Acids in the Crystalline State
Manabu Nakaya, Shinya Hayami, Ryo Ohtani, Masaaki Nakamura, Leonard F. Lindoy, Kunihisa Sugimoto
The assembly arrangement of nucleobase-appended terpyridine cobalt(II) complexes, [Co(A-C6-terpy)2](BF4)2 and [Co(T-C6-terpy)2](BF4)2 is investigated. In addition a single crystal structure of heteroleptic terpyridine cobalt(II) complexes, [Co(A-C6-terpy)(T-C6-terpy)](BF4)2 has been obtained successfully for the first time. The complex exhibited dimer ring structure through the base pairings. This result shows that use of base pairings is useful for construction of supramolecular structures. For more details, see the Full Paper by S. Hayami et al. on page 7232 ff.

Publisher URL: http://onlinelibrary.wiley.com/resolve/doi

DOI: 10.1002/chem.201783063

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