3 years ago

Twisted Aromatic Frameworks: Readily Exfoliable and Solution-Processable Two-Dimensional Conjugated Microporous Polymers

Twisted Aromatic Frameworks: Readily Exfoliable and Solution-Processable Two-Dimensional Conjugated Microporous Polymers
Iñigo Perez-Miqueo, Steven De Feyter, Aurelio Mateo-Alonso, Karol Strutyński, A. Belen Marco, Diego Cortizo-Lacalle, Giovanni Valenti, Jan Plas, Alessandro Boni, Mario Montes, Andrei N. Khlobystov, Francesco Paolucci, Manuel Melle-Franco
Twisted two-dimensional aromatic frameworks have been prepared by overcrowding the nodes with bulky and rigid substituents. The highly distorted aromatic framework with alternating out-of-plane substituents results in diminished interlayer interactions that favor the exfoliation and dispersion of individual layers in organic media. A twist of fate! A twisted two-dimensional aromatic framework was prepared by overcrowding the nodes with bulky and rigid substituents (see structure). The highly distorted aromatic framework with out-of-plane substituents results in diminished interlayer interactions, thus favoring the exfoliation and dispersion of individual layers in organic media.

Publisher URL: http://onlinelibrary.wiley.com/resolve/doi

DOI: 10.1002/anie.201700271

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