3 years ago

Kinetics and Mechanism of the Chlorate–Nitrous Acid Reaction

Kinetics and Mechanism of the Chlorate–Nitrous Acid Reaction
Rafaela T. P. Sant’Anna, Roberto B. Faria
The chlorate−nitrous acid reaction presented a complex behavior, in acid media, producing chlorine dioxide only after all nitrous acid was consumed. An isosbestic point at 312 nm indicates a 1:1 ratio between nitrate ion and nitrous acid species. This is the first time chlorine dioxide was observed to be formed by this reaction. The proposed mechanism is a significant improvement in the understanding of the complex nitrogen and chlorine aqueous chemistry.

Publisher URL: http://dx.doi.org/10.1021/acs.inorgchem.7b01477

DOI: 10.1021/acs.inorgchem.7b01477

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