Inorganic Chemistry
Inorganic Chemistry
4 years ago

Ancillary Ligand Effects upon the Photochemistry of Mn(bpy)(CO)3X Complexes (X = Br–, PhCC–)

Ancillary Ligand Effects upon the Photochemistry of Mn(bpy)(CO)3X Complexes (X = Br–, PhCC–)
Wai Yip Fan, Veeranna Yempally, Edward N. Brothers, Salvador Moncho, Faraj Hasanayn, Ashfaq A. Bengali
The photochemistry of the Mn(bpy)(CO)3X complexes [X = Br−, CCPh−] in polar coordinating solvents has been investigated. The experimental findings guided by theoretical calculations demonstrate that differences in the electronic characteristics of the anionic ligands have an important influence on the structure and reactivity of the respective solvated complexes.

Publisher URL: http://dx.doi.org/10.1021/acs.inorgchem.7b01543

DOI: 10.1021/acs.inorgchem.7b01543

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