Chemistry - A European Journal
Chemistry - A European Journal
5 years ago

Inside Back Cover: Engineering of Ruthenium(II) Photosensitizers with Non-Innocent Oxyquinolate and Carboxyamidoquinolate Ligands for Dye-Sensitized Solar Cells (Chem. Eur. J. 31/2017)

Inside Back Cover: Engineering of Ruthenium(II) Photosensitizers with Non-Innocent Oxyquinolate and Carboxyamidoquinolate Ligands for Dye-Sensitized Solar Cells (Chem. Eur. J. 31/2017)
Jonathan Rochford, Nicholas A. Lee, Sashari D. Pinnace, Ken T. Ngo
Non-innocent ligand transition metal complexes are appealing due to their remarkable redox properties imparted by the presence of extensive metal(dπ)–ligand(π) bonding. The non-innocent character derived from the mixing of ruthenium dπ and oxyquinolate or N-carboxyamidoquinolate π orbitals generates hybrid metal–ligand frontier orbitals that play a major role in contributing to an improved power conversion efficiency in a Ru non-innocent ligand sensitized DSSC device. More information can be found in the Full Paper by J. Rochford and co-workers on page 7497.

Publisher URL: http://onlinelibrary.wiley.com/resolve/doi

DOI: 10.1002/chem.201700801

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