5 years ago

Superacids Based on Pentafluoroorthotellurate Derivatives of Aluminum

Superacids Based on Pentafluoroorthotellurate Derivatives of Aluminum
Sebastian Riedel, Thomas W. Gries, Simon Steinhauer, Helmut Beckers, Anja Wiesner
Novel members of the league of extraordinary superacids, namely the Brønsted superacid H[Al(OTeF5)4] and the Lewis superacid “Al(OTeF5)3”, have been synthesized starting from AlEt3 and HOTeF5. In their Communication (DOI: 10.1002/anie.201702807), S. Riedel and co-workers describe the preparation and crystallization of five salts of the weakly coordinating anion [Al(OTeF5)4]−, which is shown in the spotlight, through the use of H[Al(OTeF5)4].

Publisher URL: http://onlinelibrary.wiley.com/resolve/doi

DOI: 10.1002/anie.201705090

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