3 years ago

Supramolecular Electronic Interactions in Porphyrin–SWCNT Hybrids through Amidinium–Carboxylate Connectivity

Supramolecular Electronic Interactions in Porphyrin–SWCNT Hybrids through Amidinium–Carboxylate Connectivity
Sonia Vela, Laura Rodríguez-Pérez, Carmen Atienza, Nazario Martín
New supramolecular (metal)porphyrin/SWCNT hybrids have been synthesized through a combination of hydrogen bond and electrostatic interactions. Our experimental findings reveal through different techniques (XPS, TGA, UV−vis, Raman, and TEM) an efficient n-doping of the SWCNT from the electron donor (metal)porphyrin through the efficient and strong amidinium–carboxylate connectivity.

Publisher URL: http://dx.doi.org/10.1021/acs.orglett.7b02239

DOI: 10.1021/acs.orglett.7b02239

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